Zinkkomplexe von Sulfonamiden Zinc Complexes of Sulfonamides

نویسندگان

  • Uwe Hartmann
  • Heinrich Vahrenkamp
چکیده

The diuretic sulfonamides furosemid (FLFur) and hydrochlorothiazid (H2Hyt) were used as ligands in zinc complexes. Spectroscopic data indicate that in [(HFur)Zn(H 2 0 )2 ]C1 0 4 and (HFur)2Zn the furosemid ligand is bound to zinc via its carboxylate and amine functions while (Fur)Zn(NH3)2 is a coordination polymer with Zn-carboxylate and Zn-sulfonimide coordination. A structure determination shows (Hyt)Zn(NH3)2 to be a coordination polymer as well, with both deprotonated sulfonamide functions forming Z n -N bonds.

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تاریخ انتشار 2013